TY - JOUR AU - Hernandez, Johana Ramirez AU - Chemla, Fabrice AU - Ferreira, Franck AU - Jackowski, Olivier AU - Oble, Julie AU - Perez-Luna, Alejandro AU - Poli, Giovanni PY - 2016/02/24 Y2 - 2024/03/28 TI - tert-Butanesulfinamides as Nitrogen Nucleophiles in Carbon–Nitrogen Bond Forming Reactions JF - CHIMIA JA - Chimia VL - 70 IS - 1-2 SE - Scientific Articles DO - 10.2533/chimia.2016.84 UR - https://www.chimia.ch/chimia/article/view/2016_084 SP - 84 AB - The use of tert-butanesulfinamides as nitrogen nucleophiles in carbon–nitrogen bond forming reactions is reviewed. This field has grown in the shadow of the general interest in N-tert-butanesulfinyl imines for asymmetric synthesis and occupies now an important place in its own right in the chemistry of the chiral amine reagent tert-butanesulfinamide. This article provides an overview of the area and emphasizes recent contributions wherein the tert-butanesulfinamides act as chiral auxiliaries or perform as nitrogen donors in metal-catalyzed amination reactions. ER -