Melt Polycondensation for the Synthesis of Polyester Amides using Kneader Reactor Technology

FH-HES Universities of Applied Sciences

Authors

  • Lucien Blanchard Haute école d'ingénierie et d'architecture Fribourg, Institute ChemTech, Boulevard de Pérolles 80, CH-1700 Fribourg, Switzerland
  • Chris Rader Haute école d'ingénierie et d'architecture Fribourg, Institute ChemTech, Boulevard de Pérolles 80, CH-1700 Fribourg, Switzerland; Adolphe Merkle Institute (AMI), Polymer Chemistry and Materials, University of Fribourg, Chemin des Verdiers 4, CH-1700 Fribourg, Switzerland
  • Ennio Vanoli Haute école d'ingénierie et d'architecture Fribourg, Institute ChemTech, Boulevard de Pérolles 80, CH-1700 Fribourg, Switzerland
  • Roger Marti Haute école d'ingénierie et d'architecture Fribourg, Institute ChemTech, Boulevard de Pérolles 80, CH-1700 Fribourg, Switzerland;, Email: roger.marti@hefr.ch

DOI:

https://doi.org/10.2533/chimia.2020.1024

PMID:

33357301

Keywords:

Kneader reactor, Polycondensation, Polyester amides, Process development

Abstract

In this work, we discuss the process development and scale-up of the melt polycondensation of polyester amides from a laboratory scale to kg-scale in a kneader reactor. We identified and optimized the most important critical parameters and produced kg-quantities of polyester amides with Mn up to 25'000 g/mol and reproducible thermal and mechanical properties. The special kneader reactor allows safe and efficient scale-up of polymerisation reactions at high temperature and viscous melts due to good mixing and efficient mass transfer.
CHIMIA Vol. 74 No. 12(2020): Radiochemistry in Switzerland

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Published

2020-12-23

Issue

Vol. 74 No. 12 (2020): Radiochemistry in Switzerland

Section

Columns, Conference Reports

Categories

License

Copyright (c) 2020 Lucien Blanchard, Chris Rader, Ennio Vanoli, Roger Marti

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

[1]
L. Blanchard, C. Rader, E. Vanoli, R. Marti, Chimia 2020, 74, 1024, DOI: 10.2533/chimia.2020.1024.