Radical Reactions of Boron-Ate Complexes Promoting a 1,2-Metallate Rearrangement

Authors

  • Nicholas D. C. Tappin Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern
  • Philippe Renaud Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern;, Email: philippe.renaud@dcb.unibe.ch

DOI:

https://doi.org/10.2533/chimia.2020.33

PMID:

32200784

Keywords:

Boronic esters, Boron-ate complexes, Cross-coupling, Inverse ylid, 1,2-metallate rearrangement, Matteson rearrangement, Radicals

Abstract

Recently there has been an explosion of interest in the synthetic community for the addition of radicals into unsaturated organoboron-ate complexes. This review will give a concise outline for radical processes involving boron-ate complexes which trigger a subsequent anionotropic rearrangement.
CHIMIA Vol. 74 No. 01-02(2020): SCS-Syngenta Symposium: Welcome to the One-electron World

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Published

2020-02-26

Issue

Vol. 74 No. 1-2 (2020): SCS-Syngenta Symposium: Welcome to the One-electron World

Section

Scientific Articles

License

Copyright (c) 2020 Nicholas D. C. Tappin, Philippe Renaud

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

[1]
Chimia 2020, 74, 33, DOI: 10.2533/chimia.2020.33.