Radical Reactions of Boron-Ate Complexes Promoting a 1,2-Metallate Rearrangement

Nicholas D. C. Tappin; Philippe Renaud

doi:10.2533/chimia.2020.33

Radical Reactions of Boron-Ate Complexes Promoting a 1,2-Metallate Rearrangement

Authors

Nicholas D. C. Tappin Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern
Philippe Renaud Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern;, Email: philippe.renaud@dcb.unibe.ch

DOI:

https://doi.org/10.2533/chimia.2020.33

PMID:

32200784

Keywords:

Boronic esters, Boron-ate complexes, Cross-coupling, Inverse ylid, 1,2-metallate rearrangement, Matteson rearrangement, Radicals

Abstract

Recently there has been an explosion of interest in the synthetic community for the addition of radicals into unsaturated organoboron-ate complexes. This review will give a concise outline for radical processes involving boron-ate complexes which trigger a subsequent anionotropic rearrangement.