Mechanistic Insights into First-row Late Transition Metal-catalysed (formal) Hydroamination of Unactivated Alkenes

Authors

  • Jérôme Hannedouche Institut de Chimie Moléculaire et des Matériaux d'Orsay UMR 8182, Université Paris-Sud, Université Paris-Saclay rue du doyen Georges Poitou, Orsay, F-91405, France;, Email: jerome.hannedouche@u-psud.fr

DOI:

https://doi.org/10.2533/chimia.2018.635

Keywords:

Alkenes, Amines, First-row late transition metal, Hydroamination, Mechanistic studies

Abstract

This short review provides a mechanistic overview of the most relevant developments into the area of intra- and intermolecular hydroamination and formal hydroamination of unactivated alkenes (excluding allenes and 1,3-dienes) promoted by first-row late transition metal catalysts involving zinc, copper, iron and cobalt. The different activation strategies and mechanistic disparities encountered with these systems will be highlighted. The relevant literature from 2012 until early 2018 has been covered.
CHIMIA Vol. 72 No. 9 (2018): Organometallics and Catalysis

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Published

2018-09-01

Issue

Vol. 72 No. 9 (2018): Organometallics and Catalysis

Section

Scientific Articles

License

Copyright (c) 2018 Swiss Chemical Society

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

[1]
J. Hannedouche, Chimia 2018, 72, 635, DOI: 10.2533/chimia.2018.635.