THQphos in Ir-catalyzed Asymmetric Allylic Substitution Reactions

Authors

  • Xiao Zhang State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China
  • Shu-Li You State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), 300072, China;, Email: slyou@sioc.ac.cn

DOI:

https://doi.org/10.2533/chimia.2018.589

Keywords:

Allylic substitution, Asymmetric catalysis, Iridium, Thqphos

Abstract

The 1,2,3,4-tetrahydroquinoline phosphoramidites (THQphos) have been found to be efficient ligands for iridium-catalyzed asymmetric allylic substitution reactions. In this short review article, an overall introduction on the development of THQphos, involving their original design, preparation, mechanistic studies, applications and features will be described.
CHIMIA Vol. 72 No. 9 (2018): Organometallics and Catalysis

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Published

2018-09-01

Issue

Vol. 72 No. 9 (2018): Organometallics and Catalysis

Section

Scientific Articles

License

Copyright (c) 2018 Swiss Chemical Society

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

[1]
X. Zhang, S.-L. You, Chimia 2018, 72, 589, DOI: 10.2533/chimia.2018.589.