Stereoselective Reactions with Chiral Schiff Base Metal Complexes

Authors

  • Andrea Gualandi ALMA MATER STUDIORUM Università di Bologna Dipartimento di Chimica "G. Ciamician" Via Selmi 2, 40126 Bologna, Italy
  • Claire Margaret Wilson University of Bath Department of Chemistry Claverton Down, Bath, BA2 7AY, UK
  • Pier Giorgio Cozzi ALMA MATER STUDIORUM Università di Bologna Dipartimento di Chimica "G. Ciamician" Via Selmi 2, 40126 Bologna, Italy. piergiorgio.cozzi@unibo.it

DOI:

https://doi.org/10.2533/chimia.2017.562

Keywords:

Catalysis, Lewis acids, Metal complexes, Schiff bases, Stereocontrol

Abstract

Chiral Schiff bases are privileged chiral ligands, capable of transmitting chiral information in many stereoselective processes. Their modular nature, the possibility to modify their electronic character, and their ability to coordinate many metals, gives these chiral ligands broad utility and these have been investigated by many research groups around the world. For more than 20 years our research group has devoted attention to the application of chiral Schiff bases in the development of new stereoselective processes and in this brief survey we present our principal results and achievements in this field.

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Published

2017-09-27

Issue

Section

Scientific Articles