Free-radical Carbo-functionalization of Olefins Using Sulfonyl Derivatives

Authors

  • Benjamin Ovadia
  • Frédéric Robert
  • Yannick Landais

DOI:

https://doi.org/10.2533/chimia.2016.34

Keywords:

Allylation, Azidation, Carbonylation, β-fragmentation, Oximation, Radical addition, Sulfones

Abstract

This review provides an overview of the recent progress made in the area of free-radical additions across the ?-system of olefins, with a focus on the role of sulfonyl derivatives as one of the reaction partners in multicomponent processes. The mechanism and utility in organic synthesis of carbo-alkenylation, alkynylation, oximation and azidation of olefins are thus discussed and illustrated with some applications in total synthesis of natural products.

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Published

2016-02-24

Issue

Section

Scientific Articles

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