Polymer-containing Organo-Polyoxometalate: Towards New Catalytic Object

Authors

  • Emmanuel Lacôte Laboratoire LHCEP (UMR 5278) Université Claude Bernard Lyon 1, Villeurbanne, France;, Email: emmanuel.lacote@univ-lyon1.fr

DOI:

https://doi.org/10.2533/chimia.2016.29

Keywords:

Catalysis, Hybrid materials, Organic–inorganic hybrids, Polymers, Polyoxometalates

Abstract

Polyoxometalates (POMs) are early transition metal oxide clusters, which form a diverse family of compounds with highly tunable shapes, sizes, charges, etc. Generating hybrid structures is an attractive path to increase the structural diversity of POMs. The present article is a personal account that retraces how we inserted polyoxometallic platforms onto polymeric chains. We focused on two main families of functionalized organo-POMs: the organotin-substituted Dawson polyoxotunstates ?1 and ?2-[P2W17O61(SnR)]7– and the Dawson vanadotungstates [P2V3W15O59{(OCH2)2-C(Et)NHC(=O)R}]5–. Herein we discuss how the connection of POMs to polymers affects the self-assembly of the polymers and the catalytic properties of the polyoxometalates.

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Published

2016-02-24

How to Cite

[1]
E. Lacôte, Chimia 2016, 70, 29, DOI: 10.2533/chimia.2016.29.

Issue

Section

Scientific Articles