A Convenient Synthetic Route to Partial-Cone p-Carboxylatocalix[4]arenes

Authors

  • Robyn E. Fairbairn Institute of Chemical Sciences Heriot-Watt University Riccarton, Edinburgh, UK
  • Simon J. Teat Advanced Light Source Lawrence Berkeley National Laboratory Berkeley CA 94720, USA
  • Kevin J. Gagnon Advanced Light Source Lawrence Berkeley National Laboratory Berkeley CA 94720, USA
  • Scott J. Dalgarno Institute of Chemical Sciences Heriot-Watt University Riccarton, Edinburgh, UK. S.J.Dalgarno@hw.ac.uk

DOI:

https://doi.org/10.2533/chimia.2015.516

Keywords:

P-carboxylatocalix[4]arene, Supramolecular assemblies

Abstract

p-Carboxylatocalix[n]arenes have emerged as useful building blocks for the construction of a diverse range of supramolecular assemblies. A convenient route to a p-carboxylatocalix[4]arene that is locked in a partial-cone conformation is presented. The conformation gives the molecule markedly different topological directionality relative to those previously used in self- and metal-directed assembly studies.

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Published

2015-09-30

Issue

Section

Scientific Articles