Synthesis and Reactivity of Zn–Biphenyl Metal–Organic Frameworks, Introducing a Diphenylphosphino Functional Group

Authors

  • Marco Ranocchiari Laboratory of Catalysis and Sustainable Chemistry Paul Scherrer Institute CH-5232 Villigen PSI, Switzerland. marco.ranocchiari@psi.ch
  • Jeroen Anton van Bokhoven Laboratory of Catalysis and Sustainable Chemistry Paul Scherrer Institute CH-5232 Villigen PSI, Switzerland; Laboratory for Chemical and Bioengineering ETH Zurich Wolfgang Pauli Strasse, 10 CH-8093 Zürich, Switzerland. jeroen.vanbokhoven@chem.ethz.ch

DOI:

https://doi.org/10.2533/chimia.2013.397

Keywords:

Metal–organic frameworks, Mof-5

Abstract

Structural features, synthesis, and reactivity of Zn–biphenyl metal–organic frameworks with MOF-5 topology are presented to show the chemical flexibility of such materials and to demonstrate the challenges that can be encountered and solved to avoid interpenetration. We introduce the synthesis of a Zn–biphenyl MOF with diphenylphosphino functionalization and illustrate its structural and chemical properties.
CHIMIA Vol. 67 No. 6(2013): Coordination Polymers: From Structures to Applications

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Published

2013-06-26

Issue

Vol. 67 No. 6 (2013): Coordination Polymers: From Structures to Applications

Section

Scientific Articles

License

Copyright (c) 2013 Swiss Chemical Society

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

[1]
M. Ranocchiari, J. A. van Bokhoven, Chimia 2013, 67, 397, DOI: 10.2533/chimia.2013.397.