R-isophthalic Acid-based Coordination Polymers (R = Hydrogen or Bromine)

Authors

  • Ren Zhang Department of Chemistry and Chemical Biology Rutgers University 610 Taylor Road, Piscataway, NJ, 08854, USA
  • Qihan Gong Department of Chemistry and Chemical Biology Rutgers University 610 Taylor Road, Piscataway, NJ, 08854, USA
  • Thomas J. Emge Department of Chemistry and Chemical Biology Rutgers University 610 Taylor Road, Piscataway, NJ, 08854, USA
  • Debasis Banerjee Department of Chemistry and Chemical Biology Rutgers University 610 Taylor Road, Piscataway, NJ, 08854, USA
  • Jing Li Department of Chemistry and Chemical Biology Rutgers University 610 Taylor Road, Piscataway, NJ, 08854, USA. jingli@rutgers.edu

DOI:

https://doi.org/10.2533/chimia.2013.393

Keywords:

1d and 2d polymers, Coordination polymers, Isophthalic acid, N ligands, Solvothermal reaction

Abstract

Three new R-isophthalic acid-based (R = H or Br) coordination polymers have been designed and synthesized. By changing the N-containing ligand in the system, we are able to tune the dimensionality of coordination polymers from one-dimension (1D) to two-dimensions (2D) with the same basic building unit. Also, different metal ions can be incorporated into the same structures. Compound 1 [Cu(bipa)(py)2]·0.5(H2O) (H2bipa = 5-bromoisophthalic acid; py = pyridine) and compound 2 [Co(bipa)(py)2] are 1D chain structures. Compound 3 [Cu8(ipa)8(bpe)8]·2(bpe)·4(H2O) (bpe=1,2-bis(4-pyridyl)ethane) is a 2D layered structure.
CHIMIA Vol. 67 No. 6(2013): Coordination Polymers: From Structures to Applications

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Published

2013-06-26

Issue

Vol. 67 No. 6 (2013): Coordination Polymers: From Structures to Applications

Section

Scientific Articles

License

Copyright (c) 2013 Swiss Chemical Society

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

[1]
R. Zhang, Q. Gong, T. J. Emge, D. Banerjee, J. Li, Chimia 2013, 67, 393, DOI: 10.2533/chimia.2013.393.