Dynamical Processes in Rydberg-Stark Deceleration and Trapping of Atoms and Molecules

Authors

  • Christian Seiler SCS-Metrohm Foundation Award for best oral presentation, Laboratory of Physical Chemistry ETH Zürich Wolfgang-Pauli-Str. 10 CH-8093 Zürich, Switzerland
  • Stephen D. Hogan Laboratory of Physical Chemistry ETH Zürich Wolfgang-Pauli-Str. 10 CH-8093 Zürich, Switzerland
  • Frédéric Merkt Laboratory of Physical Chemistry ETH Zürich Wolfgang-Pauli-Str. 10 CH-8093 Zürich, Switzerland. feme@xuv.phys.chem.ethz.ch

DOI:

https://doi.org/10.2533/chimia.2012.208

Keywords:

Blackbody radiation, Cold molecules, Rydberg states, Stark deceleration

Abstract

The interaction between inhomogeneous electric fields and the large electric dipole moments of atoms and molecules in Rydberg states of high principal quantum number can be used to efficiently accelerate and decelerate atoms and molecules in the gas phase. We describe here how hydrogen atoms and molecules initially moving with velocities of ?600 m/s in supersonic beams can be decelerated to zero velocity and loaded into electric traps. The long observation times that are made possible by the electrostatic trapping enables one to study slow relaxation processes. Experiments are presented in which we have observed photoionization processes and transitions between Rydberg states induced by blackbody radiation at temperatures between 10 K and 300 K on a time scale of several milliseconds. Comparison of these processes in Rydberg states of H and H2 suggests the importance, in H2, of collisional processes and of the process of blackbody-radiation-induced predissociation.

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Published

2012-04-25

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