New Developments in Aromatic Halogenation, Borylation, and Cyanation

Authors

  • Di Qiu Peking University, China
  • Fanyang Mo Beijing Institute of Technology, P. R. of China
  • Zhitong Zheng Peking University, China
  • Yan Zhang Lanzhou University, China
  • Jianbo Wang Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education College of Chemistry, Peking University Beijing 100871, China. wangjb@pku.edu.cn

DOI:

https://doi.org/10.2533/chimia.2011.909

Keywords:

Au-catalyzed, Borylation, Cyanation, Fe-catalyzed, Green chemistry, Halogenation, Metal-free reactions

Abstract

Several green procedures have been developed for synthesizing functionalized aromatics: i) AuCl3-catalyzed halogenation of aromatic compounds, including aryl boronates; ii) Fe2O3-catalyzed direct aromatic C–H bond borylation; iii) Pd-catalyzed direct cyanation of indoles; iv) direct conversion of arylamines to pinacol boronates.

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Published

2011-12-14

Issue

Section

Scientific Articles