Artificial Metalloenzymes for Enantioselective Catalysis Based on the Biotin-Avidin Technology
DOI:
https://doi.org/10.2533/chimia.2008.956Keywords:
Artificial metalloenzymes, Asymmetric catalysis, Biotin-(strept)avidin technology, EnantioselectivityAbstract
Artificial metalloenzymes, based on the incorporation of a biotinylated catalytically active organometallic moiety within streptavidin, offer an attractive alternative to homogeneous, heterogeneous and enzymatic catalysis. In this account, we outline our recent results and implications in the developments of such artificial metalloenzymes for various asymmetric transformations, including hydrogenation, transfer hydrogenation, allylic alkylation and sulfoxidation.Downloads
Published
2008-12-17
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Scientific Articles
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Copyright (c) 2008 Swiss Chemical Society
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How to Cite
[1]
J. Mao, T. R. Ward, Chimia 2008, 62, 956, DOI: 10.2533/chimia.2008.956.