Stereoselective Radical Translocations

Authors

  • Philippe Renaud
  • Florent Beaufils
  • Fabrice Dénès
  • Laurence Feray
  • Christoph Imboden
  • Nikolai Kuznetsov

DOI:

https://doi.org/10.2533/chimia.2008.510

Keywords:

H-abstraction, C-h activation, Asymmetric synthesis, Radicals, Stereochemistry

Abstract

The stereochemical outcome of intramolecular radical mediated hydrogen transfer (= radical translocation) is discussed. Low to excellent levels of stereocontrol are observed making such processes attractive for applications in target-oriented synthesis.

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Published

2008-06-25

Issue

Section

Scientific Articles