Chiral Phosphoric Acid Diesters as Ligands in Asymmetric Transition Metal Catalyzed Hydrogenation

Authors

  • Manfred T. Reetz
  • Thorsten Sell
  • Richard Goddard

DOI:

https://doi.org/10.2533/000942903777679316

Keywords:

Asymmetric catalysis, Chirality, Hydrogenation, Iridium, Palladium, Phosphorus ligands, Rhodium

Abstract

A chiral phosphoric acid diester, specifically the BINOL-based derivative, has been used for the first time in Rh-, Ir-, and Pd-catalyzed hydrogenation of olefins and imines, giving ee-values of up to 85%.

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Published

2003-05-01

Issue

Vol. 57 No. 5 (2003): Combinatorial Chemistry

Section

Scientific Articles

License

Copyright (c) 2003 Swiss Chemical Society

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

[1]
M. T. Reetz, T. Sell, R. Goddard, Chimia 2003, 57, 290, DOI: 10.2533/000942903777679316.