Chiral Phosphoric Acid Diesters as Ligands in Asymmetric Transition Metal Catalyzed Hydrogenation
Keywords:Asymmetric catalysis, Chirality, Hydrogenation, Iridium, Palladium, Phosphorus ligands, Rhodium
AbstractA chiral phosphoric acid diester, specifically the BINOL-based derivative, has been used for the first time in Rh-, Ir-, and Pd-catalyzed hydrogenation of olefins and imines, giving ee-values of up to 85%.
How to Cite
M. T. Reetz, T. Sell, R. Goddard, Chimia 2003, 57, 290, DOI: 10.2533/000942903777679316.
Copyright (c) 2003 Swiss Chemical Society
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