Stabilization of Molecular LiF, LiFHF, and Na2SiF6 Using Metallamacrocyclic Hosts

Authors

  • Marie-Line Lehaire
  • Kay Severin

DOI:

https://doi.org/10.2533/000942903777679550

Keywords:

Chemosensor, Fluoride, Lithium, Metallamacrocycle, Sodium, Stabilization

Abstract

The molecular forms of LiF, LiFHF and Na2SiF6 have been stabilized using trinuclear metalla-macrocyclic complexes of (cymene)RuII, (Cp*)RhIII and (Cp*)IrIII as specific receptors. The host–guest complexes were characterized by NMR spectroscopy and single crystal X-ray diffraction. Based on these results, a highly selective chemosensor for fluoride anions has been developed.

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Published

2003-04-01

Issue

Vol. 57 No. 4 (2003): Laureates: Awards and Honors (SCS)

Section

Scientific Articles

License

Copyright (c) 2003 Swiss Chemical Society

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

[1]
M.-L. Lehaire, K. Severin, Chimia 2003, 57, 190, DOI: 10.2533/000942903777679550.