Chemical Pressure

Authors

  • Andreas Hauser
  • Nahid Amstutz
  • Sandra Delahaye
  • Asmaâ Sadki
  • Sabine Schenker
  • Regula Sieber
  • Mohamed Zerara

DOI:

https://doi.org/10.2533/000942902777679858

Keywords:

Chemical pressure, [co(bpy)3]2 , [fe(bpy)3]2 , Guest-host interaction, Intersystem crossing, Luminescence, Radiationless deactivation, [ru(bpy)3]2 , Spin-crossover

Abstract

The physical and photophysical properties of three classic transition metal complexes, namely [Fe(bpy)3]2+, [Ru(bpy)3]2+, and [Co(bpy)3]2+, can be tuned by doping them into a variety of inert crystalline host lattices. The underlying guest-host interactions are discussed in terms of a chemical pressure.

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Published

2002-12-01