Metal Phosphides and Zeolite-like Mesoporous Materials as Catalysts

Authors

  • Roel Prins Department of Chemistry, Swiss Federal Institute of Technology, ETH Hönggerberg, CH-8093 Zürich
  • Gerhard Pirngruber
  • Thomas Weber

DOI:

https://doi.org/10.2533/chimia.2001.791

Keywords:

Catalysis, Grafting, Hydrodenitrogenation, Mcm-41, Metal phosphides

Abstract

Two new classes of materials, which we developed and use in our catalytic research, are described. Metal phosphides are studied for their use as model compounds for hydrodenitrogenation catalysis. M41S type materials contain mesopores, which enhance diffusion and, thus, the effectiveness of zeolitic materials in liquid-phase reactions. After grafting with sulfonic acid groups, they are used as wide-pore solid acids.

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Published

2001-10-31