Recent Developments in Asymmetric Catalysis
DOI:
https://doi.org/10.2533/chimia.2001.708Keywords:
Allylic substitution, Asymmetric catalysis, Chiralligands, Enantioselective hydrogenationAbstract
Asymmetric catalysis has long been dominated by C2-symmetric bidentate ligands. More recently, sterically and electronically unsymmetrical ligands have found increasing attention. An important family of these are the phosphinooxazoline (PHOX) ligands incorporating one P-coordinating and one N-coordinating unit. Important applications of PHOX ligands include Pd-catalyzed allylic substitution and Ir-catalyzed hydrogenation.
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2001-09-26
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Copyright (c) 2001 Swiss Chemical Society
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How to Cite
[1]
A. Pfaltz, Chimia 2001, 55, 708, DOI: 10.2533/chimia.2001.708.