Preparation of Novel Enantiopure Ferrocenyl-Based Ligands for Asymmetric Catalysis

Authors

  • Thomas Sturm
  • Li Xiao
  • Walter Weissensteiner Universität Wien, Institut für Organische Chemie, Währinger Straße 38, A-1090 Wien

DOI:

https://doi.org/10.2533/chimia.2001.688

Keywords:

Asymmetric catalysis, Ferrocenes, Phosphines

Abstract

Novel enantiopure ferrocene-based aminophosphine and diphosphine ligands for asymmetric catalysts have been developed. In all cases a highly flexible synthetic approach allowed access to ligands with different ferrocenyl backbones and with a variety of functional group patterns. Procedures for the synthesis of six families of ligands with either a homo- or heteroannularly bridged ferrocene, ferrocenylmethyl, biferrocene, biferroceno-azepine or ferrocenyl-aryl framework are described in detail.

Downloads

Published

2001-09-26

Issue

Section

Scientific Articles

How to Cite