Ligand Effects on the Rate and Mechanism of Solvent Exchange at Rhodium(III) and Iridium(III)

Authors

  • Antonio Cusanelli
  • Lynda Nicula-Dadci
  • Urban Frey
  • André E. Merbach

DOI:

https://doi.org/10.2533/chimia.1996.618

Abstract

The rate constants and activation parameters for solvent exchange for a series of RhIII and IrIII complexes of the form [M(H2O)6]3+ (M = Rh or Ir) and [Cp*M(S)3]2+ (M = Rh or Ir, and S = H2O, MeCN, or Me2SO) have been determined by NMR spectroscopy as a function of free-solvent concentration, temperature, and pressure, and the mechanisms for the respective exchange processes have been inferred.

Downloads

Published

1996-12-18

How to Cite

[1]
A. Cusanelli, L. Nicula-Dadci, U. Frey, A. E. Merbach, Chimia 1996, 50, 618, DOI: 10.2533/chimia.1996.618.

Issue

Section

Scientific Articles