Reactivity of Allenes towards Iron Carbonyl Complexes
DOI:
https://doi.org/10.2533/chimia.1994.362Abstract
A series of monosubstituted allenes was reacted with Fe2(CO)9 to give dinuclear iron-carbonyl complexes containing organic ligands derived either from monomeric or dimerized allene. A mechanism of formation is proposed based on isolated intermediates. These intermediates point to an allene dimerization via addition of a reactive allene iron complex to free allene. Unusual chemical shifts were observed for many resonances in the 1H- and 13C-NMR spectra of the new compounds.
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1994-09-28
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Copyright (c) 1994 Swiss Chemical Society
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How to Cite
[1]
A. M. Kuonen, J. Raemy, T. A. Jenny, Chimia 1994, 48, 362, DOI: 10.2533/chimia.1994.362.