Fixierung von Sulfonsäure-hydraziden an dreikernigen Ruthenium-Clustern: Synthese und Struktur von (μ₂-H)Ru₃(CO)₉[μ₃-η²-H₂NNS(O)₂Mes]
DOI:
https://doi.org/10.2533/chimia.1993.196Abstract
Sulfonic hydrazides were found to react thermally with Ru3(CO)12 without cleavage of the N–N bond resulting in the formation of trinuclear hydrazido clusters. The X-ray structure analysis of the derivative (μ2-H)Ru3(CO)9[μ3-η2-H2NNS(O)2Mes] shows a triangular Ru3 framework capped by an intact N–N unit.
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1993-06-30
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Copyright (c) 1993 Swiss Chemical Society
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How to Cite
[1]
G. Rheinwald, H. Stoeckli-Evans, G. Süss-Fink, Chimia 1993, 47, 196, DOI: 10.2533/chimia.1993.196.