Triafulven- und Calicen-Vorstufen für retro-Diels-Alder Reaktionen

Authors

  • Michel Mühlebach
  • Markus Neuenschwander

DOI:

https://doi.org/10.2533/chimia.1992.382

Abstract

An attractive concept for the synthesis of triafulvene (1) and calicene (2) by retro-Diels-Alder reaction (RDA reaction) of precursors 3 and 4 is presented. Precursors 3 and 4 are easily available in three steps starting with dibenzobarrelene (5). First thermal-fragmentation experiments are summarized.

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Published

1992-09-30