Acetoxymaleic Anhydride as Ketene Equivalent in the Diels-Alder Reaction

Authors

  • Ernest Wenkert
  • Christian Vial
  • Ferdinand Näf

DOI:

https://doi.org/10.2533/chimia.1992.95

Abstract

Acetoxymaleic anhydride (AMA) has been shown to be a versatile ketene equivalent in the Diels-Alder reaction for the conversion of 1,3-dienes into cyclohexanones. The new transformation has been applied to an alternate synthesis of methyl cis-dihydrojasmonate, an important jasmine fragrance, and to several model systems.

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Published

1992-04-29