Asymmetric Catalysis in the Cyclometallation Reaction

Authors

  • Vyatcheslav I. Sokolov Institute of Organo-Element Compounds, Moscow, U.S.S.R.
  • Ludmila L. Troitskaya Institute of Organo-Element Compounds, Moscow, U.S.S.R.

DOI:

https://doi.org/10.2533/chimia.1978.122

Abstract

The formation of optically active cyclopalladated products starting from dimethylaminomethylferrocene has been observed for the first time using the salts of optically active acids as basic catalysts. This seems to be a unique example for the non-intra-molecular asymmetric induction of planar chirality. The maximum enantiomeric excess thus far obtained is nearly 12%.

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Published

1978-04-30

Issue

Vol. 32 No. 4 (1978): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1978 Vyatcheslav I. Sokolov

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
V. I. Sokolov, L. L. Troitskaya, Chimia 1978, 32, 122, DOI: 10.2533/chimia.1978.122.