Thermolyse des 1:1-Adduktes aus «Münchnon» und Cyclopentadienchinon

Authors

  • Josef Lukáč Organisch-chemisches Institut der Universität Zürich
  • Heinz Heimgartner Organisch-chemisches Institut der Universität Zürich
  • Hans Schmid Organisch-chemisches Institut der Universität Zürich

DOI:

https://doi.org/10.2533/chimia.1977.138

Abstract

The thermolysis of the 1:1-cycloadduct 3, synthesized by the addition of cyclopentadienequinone (1) and 3-methyl-2,4-diphenyl-5-oxazolone (2), yields 5,6-dihydro-2-methyl-1,3-diphenyl-2H-isoindol-4,7-dione (5) and not the tetracyclic diketone 4 (cf. [2]). The structure of 5 is elucidated by spectral data and by dehydrogenation to the 2 H-isoindole-4,7-dione 6.

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Published

1977-04-30

Issue

Section

Kurze Mitteilungen

How to Cite

[1]
J. Lukáč, H. Heimgartner, H. Schmid, Chimia 1977, 31, 138, DOI: 10.2533/chimia.1977.138.