Die Horner-Variante der Wittig-Reaktion: unter milden Bedingungen durchführbar und mit stereochemischen Optionen ausgestattet

Authors

  • M. Schlosser Institut de chimie organique de l’Université de Lausanne
  • Huynh Ba Tuong Institut de chimie organique de l’Université de Lausanne

DOI:

https://doi.org/10.2533/chimia.1976.197

Abstract

Olefin syntheses by means of metallated phosphine oxides may be carried out at room temperature. The configuration of a double-bond present in the starting material can be conserved throughout the whole reaction sequence. Moreover the new double-bond forms with extreme trans-selectivity, provided that the “PO-ylid” reagent is stabilized by an electron attracting group such as vinyl or phenyl.

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Published

1976-03-31

Issue

Vol. 30 No. 3 (1976): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1976 M. Schlosser

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
M. Schlosser, H. Ba Tuong, Chimia 1976, 30, 197, DOI: 10.2533/chimia.1976.197.