Functionalized Amide Chlorides: 5-Dimethylamino-1H-Tetrazoles from N,N-Dimethyl-Azidochloromethylenimonium Chloride and Primary amines

Authors

  • H.G. Viehe Université de Louvain, Laboratoire de Chimie Organique Place Louis-Pasteur B-1348 Louvain-la-Neuve, Belgium
  • P. George Université de Louvain, Laboratoire de Chimie Organique Place Louis-Pasteur B-1348 Louvain-la-Neuve, Belgium

DOI:

https://doi.org/10.2533/chimia.1975.209

Abstract

Sodium azide or trimethylsilylazide react with N,N-dimethylphosgenimonium chloride by monosubstitution yielding N,N-dimethyl-azidochloromethylen-imonium chloride which can be isolated. This compound is characterized both spectroscopically and by facile reactions with primary amines affording 1-substituted-5-dimethyl-amino-tetrazoles.

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Published

1975-05-31

Issue

Vol. 29 No. 5 (1975): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1975 H.G. Viehe

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
H. Viehe, P. George, Chimia 1975, 29, 209, DOI: 10.2533/chimia.1975.209.