The Synthesis of a Strained Bridgehead Olefin by an Intramolecular Wittig Reaction

Authors

  • Konrad B. Becker Institut für Organische Chemie der Universität Basel Sankt-Johanns-Ring 19, 4056 Basel

DOI:

https://doi.org/10.2533/chimia.1974.726

Abstract

A number of olefins with the double bond at the bridgehead was synthesized by an intramolecular Wittig reaction starting from 2-(bromoalkyl) cyclanones. The ring closure of 3-(3-oxocyclohexyl) propyltriphenylphosphonium bromide leads to the strained bridgehead olefin (“Bredt-olefin”) bicyclo[3.3.l]non-1-ene. Some reactions of this olefin were studied.

Downloads

Published

1974-12-31

Issue

Vol. 28 No. 12 (1974): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1974 Konrad B. Becker

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
K. B. Becker, Chimia 1974, 28, 726, DOI: 10.2533/chimia.1974.726.