Pouvoir discriminatoire du palladium(II) dans les réactions de substitution de ses chlorocomplexes avec les diamines

Authors

  • R. Ernst Institut de chimie minérale et analytique, Université de Lausanne Place du Château 3, CH-1005 Lausanne
  • R. Roulet Institut de chimie minérale et analytique, Université de Lausanne Place du Château 3, CH-1005 Lausanne

DOI:

https://doi.org/10.2533/chimia.1974.347

Abstract

The rate constants of the substitution reactions of chloride and water by various diamines in chlorocomplexes of Pd(II) have been determined spectrophotometrically. The mechanism of substitution is associative and the comparison with the corresponding Pt(II) complexes shows that the discriminating power of Pd(II) is smaller than the one of Pt(II).

Downloads

Published

1974-07-31

Issue

Vol. 28 No. 7 (1974): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1974 R. Ernst

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
R. Ernst, R. Roulet, Chimia 1974, 28, 347, DOI: 10.2533/chimia.1974.347.