The Reaction of 2-Aminopyridines with Ethyl Diazoacetate

Authors

  • B. Doma Department of Chemistry, University of Ljubljana 61000 Ljubljana (Yugoslavia)
  • B. Verček Department of Chemistry, University of Ljubljana 61000 Ljubljana (Yugoslavia)
  • B. Stanovnik Department of Chemistry, University of Ljubljana 61000 Ljubljana (Yugoslavia)
  • M. Tišler Department of Chemistry, University of Ljubljana 61000 Ljubljana (Yugoslavia)

DOI:

https://doi.org/10.2533/chimia.1974.235

Abstract

It has been found that ethyl diazoacetate reacted with 2- amino-pyridines to give the corresponding 2-carbethoxy- methylaminopyridines (1). In m-xylene as solvent, thermal decomposition of the diazo ester proceeded with preferential attack on m-xylene to give a mixture of isomeric ethyl dimethylcycloheptatrienecarboxylates (2, 3 and 4).

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Published

1974-05-31

Issue

Vol. 28 No. 5 (1974): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1974 B. Doma

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
B. Doma, B. Verček, B. Stanovnik, M. Tišler, Chimia 1974, 28, 235, DOI: 10.2533/chimia.1974.235.