Die Kristallstrukturen von Cadmiumhexacyanokobaltat(III), Cd3[Co(CN)6]2 und Cadmiumhexacyanokobaltat(III)-Hydrat, Cd3[Co(CN)6]2  •  x H2O

Authors

  • G. Ron Institut für Anorganische Chemie der Universität Bern, Freiestraße3, CH-3000 Bern 9
  • A. Ludi Institut für Anorganische Chemie der Universität Bern, Freiestraße3, CH-3000 Bern 9
  • P. Engel Abteilung für Kristallographie der Universität Bern

DOI:

https://doi.org/10.2533/chimia.1973.77

Abstract

The crystal structures of Cd3[Co (CN)6]2 • x H2O and Cd3[Co(CN)6]2 have been determined by counter methods. The lattice constants of the cubic face-centered cell is a = 10.576 (4) Å for both compounds. The least-squares refinement gave R-factors of 10.5 and 7.3% for the hydrate and the anhydrous crystal, respectively. The dehydration does not affect the interatomic distances. The Co–C, C–N, and Cd–N distances are 1.91, 1.13, and 2.25 Å, respectively.

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Published

1973-02-28

Issue

Vol. 27 No. 2 (1973): Forschung/Research

Section

Articles

License

Copyright (c) 1973 G. Ron

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
G. Ron, A. Ludi, P. Engel, Chimia 1973, 27, 77, DOI: 10.2533/chimia.1973.77.