Asymmetric Hydrocarboxylation of Olefines by Chiral Palladium Complexes

Authors

  • Carlo Botteghi Technisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, Zürich
  • Giambattista Consiglio Technisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, Zürich
  • Piero Pino Technisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, Zürich

DOI:

https://doi.org/10.2533/chimia.1973.477

Abstract

Asymmetric induction up to 14% have been obtained in the hydrocarboxylation of olefinic hydrocarbons with carbon monoxide and alcohols in the presence of PdCl2 and (–)-DIOP (= 2,3-O-isopropylidene-2,3-dihydroxy-1,4- bis(diphenylphosphino)butane).

 

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Published

1973-09-30

Issue

Vol. 27 No. 9 (1973): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1973 Carlo Botteghi

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
C. Botteghi, G. Consiglio, P. Pino, Chimia 1973, 27, 477, DOI: 10.2533/chimia.1973.477.