Der Mechanismus der Umlagerung substituierter Aminoacrylderivate II

Authors

  • M. Neuenschwander Institut für Organische Chemie der Universität Bern
  • A. Niederhauser Institut für Organische Chemie der Universität Bern

DOI:

https://doi.org/10.2533/chimia.1973.379

Abstract

The acid-catalysed reaction of 3-chloro-3-dimethylamino-propenal (2a, X=Cl), labelled at position 1 with 13C, yields 3-chloro-N,N-dimethyl-acrylamide (3a, X=Cl), containing the label exclusively at position 3. This result supports a mechanism including oxetenes as intermediates.

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Published

1973-07-31

Issue

Vol. 27 No. 7 (1973): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1973 M. Neuenschwander

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
M. Neuenschwander, A. Niederhauser, Chimia 1973, 27, 379, DOI: 10.2533/chimia.1973.379.