Preparation and Hydrolysis of Secondary Diasulfones

Authors

  • B. Michel Institut de chimie organique de l’Université de Lausanne
  • J.F. McGarrity Institut de chimie organique de l’Université de Lausanne
  • H. Dahn Institut de chimie organique de l’Université de Lausanne

DOI:

https://doi.org/10.2533/chimia.1973.320

Abstract

Two secondary α-diazosulfones, 1-tosyl-1-diazo-ethane (I) and 1-tosyl-1-diazo-isobutane (II) have been prepared and characterised. The corresponding alcohols produced by acid hydrolysis are unstable and decompose to aldehyde and p-toluene-sulfinic acid; the olefins also formed in the acid hydrolysis of I and II were found to undergo further transformations.

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Published

1973-06-30

Issue

Vol. 27 No. 6 (1973): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1973 B. Michel

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
B. Michel, J. McGarrity, H. Dahn, Chimia 1973, 27, 320, DOI: 10.2533/chimia.1973.320.