Asymmetric Olefines Hydroformylation III: Asymmetric Induction by Rhodium Complexes Using (—)-2,3-O-Isopropylidene- 2,3-Dihydroxy-1,4-Bis(Diphenylphosphino)Butane as Chiral Ligand

Authors

  • Christian Salomon Technisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, Zürich
  • Giambattista Consiglio Technisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, Zürich
  • Carlo Botteghi Technisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, Zürich
  • Piero Pino Technisch-Chemisches Laboratorium der Eidgenössischen Technischen Hochschule, Zürich

DOI:

https://doi.org/10.2533/chimia.1973.215_2

Abstract

RhH(CO)(PPh3)3 in the presence of (—)-DIOP promotes asymmetric hydroformylation of aromatic olefines at atmospheric pressure and low temperature ; the asymmetric induction reaches in the case of styrene 25%. 

DIOP: abbreviation for 2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane

 

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Published

1973-04-30

Issue

Vol. 27 No. 4 (1973): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1973 Christian Salomon

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
C. Salomon, G. Consiglio, C. Botteghi, P. Pino, Chimia 1973, 27, 215, DOI: 10.2533/chimia.1973.215_2.