Reversible Reaction of Cobalt(II) Tetrasulfophthalocyanine with Molecular Oxygen

Authors

  • J. Vepřek-Šiška Institute of Inorganic Chemistry Czechoslovak Academy of Sciences, Prague
  • E. Schwertnerová Institute of Inorganic Chemistry Czechoslovak Academy of Sciences, Prague
  • D.M. Wagnerová Institute of Inorganic Chemistry Czechoslovak Academy of Sciences, Prague

DOI:

https://doi.org/10.2533/chimia.1972.75

Abstract

Absorption spectra of solutions of Co(II), Fe(III) and Mn III) tetrasulfophthalocyanines have been studied under aerobic and anaerobic conditions. CoTSP reacts reversibly with molecular oxygen forming a stable oxygen adduct. The oxygen adduct with FeTSP is stable only in neutral solution and its formation is not fully reversible. No reaction of MnTSP with oxygen has been found.

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Published

1972-02-28

Issue

Vol. 26 No. 2 (1972): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1972 J. Veprek-Siska

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
J. Vepřek-Šiška, E. Schwertnerová, D. Wagnerová, Chimia 1972, 26, 75, DOI: 10.2533/chimia.1972.75.