Oxidative Cleavage of Aromatic Azines with Periodic Acid; MO Model for the Reaction Intermediate

Authors

  • Alexander J. Fatiadi Analytical Chemistry Division, Institute for Materials Research, National Bureau of Standards, Washington (D. C.) 20234 (U.S.A.)

DOI:

https://doi.org/10.2533/chimia.1972.70

Abstract

Cleavage of benzalazine (and other azines) with periodic acid may initially involve, as a single step, the addition of IO4- (or its hydrate) across the conjugated azine system, to give an iodate I (V) complex; this view is supported from MO symmetry rules. 

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Published

1972-02-28

Issue

Vol. 26 No. 2 (1972): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1972 Alexander J. Fatiadi

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
A. J. Fatiadi, Chimia 1972, 26, 70, DOI: 10.2533/chimia.1972.70.