The Absolute Configuration of 2,7-Disubstituted Triptycenes as Determined by the Chemical Correlation

Authors

  • M. Kuritani Department of Chemistry, Faculty of Science, Osaka University Toyonaka, Osaka, 560, Japan
  • Y. Sakata Department of Chemistry, Faculty of Science, Osaka University Toyonaka, Osaka, 560, Japan
  • F. Ogura Department of Chemistry, Faculty of Science, Osaka University Toyonaka, Osaka, 560, Japan
  • M. Nakagawa Department of Chemistry, Faculty of Science, Osaka University Toyonaka, Osaka, 560, Japan

DOI:

https://doi.org/10.2533/chimia.1972.470

Abstract

The absolute configuration of optically active 2,5,7-trisubstituted triptycenes deduced from the rigorous analysis of their CD spectra based on molecular exciton theory was found to be consistent with that determined by “the revised X-ray method”. In order to get further information, the absolute configuration of 2,7-discustituted triptycene was correlated with that of 2,5,7-trisubstituted triptycenes.

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Published

1972-09-30

Issue

Vol. 26 No. 9 (1972): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1972 M. Kuritani

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
M. Kuritani, Y. Sakata, F. Ogura, M. Nakagawa, Chimia 1972, 26, 470, DOI: 10.2533/chimia.1972.470.