Synthese und Reaktivität von Quadratsäure-Iminiumchloriden

4. Mitteilung über Polycarbonylverbindungen

Authors

  • Gunther Seitz Fachbereich Pharmazie und Lebensmittelchemie der Universität, D-355 Marburg/Lahn, Marbacher Weg 6
  • Hartmut Morck Fachbereich Pharmazie und Lebensmittelchemie der Universität, D-355 Marburg/Lahn, Marbacher Weg 6

DOI:

https://doi.org/10.2533/chimia.1972.368

Abstract

Reaction of substituted diamides of squaric acid with various halogenating agents such as thionyl chloride or carbonyl chloride yields the halogenated compounds 4 ⇄ 5 (X = Cl-), which can be converted to the iminium halides 5a-d by addition of antimony pentachloride. These compounds are strong electrophiles. Their reactions with water, amines and methylen-active compounds are described.

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Published

1972-07-31

Issue

Vol. 26 No. 7 (1972): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1972 Gunther Seitz

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
G. Seitz, H. Morck, Chimia 1972, 26, 368, DOI: 10.2533/chimia.1972.368.