Darstellung und Charakterisierung der vier isomeren [2.2](2,5)Pyridinophane

Authors

  • J. Bruhin Institut für organische Chemie der Universität Bern; Ciba-Geigy AG, Basel, Forschungslaboratorien der Division Farbstoffe
  • W. Jenny Institut für organische Chemie der Universität Bern; Ciba-Geigy AG, Basel, Forschungslaboratorien der Division Farbstoffe

DOI:

https://doi.org/10.2533/chimia.1971.308

Abstract

The Hofmann-l,6-elimination reaction of 2-methyl-picolinyl(5)-trimethylammonium hydroxide led to a mixture of isomeric [2.2](2,5)pyridinophanes in good yield. All four possible isomeres are separated by gas chromatography in pure state. The 1H-NMR spectra of [2.2](2,5)pyridinophanes show pseudo-geminal and pseudo-ortho downfield shifts. 

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Published

1971-09-30

Issue

Vol. 25 No. 9 (1971): Forschung/Research

Section

Kurze Mitteilungen

License

Copyright (c) 1971 J. Bruhin

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
J. Bruhin, W. Jenny, Chimia 1971, 25, 308, DOI: 10.2533/chimia.1971.308.